Additives for PVC in footwear

PVC additives for footwear — sandals, soles, insoles and boots

Few PVC industries are as penny-sensitive as footwear. Here, the conversation starts with price and availability, but ends up with technical details that determine whether a pair is rejected: the sole abrasion resistance, the cold flexibility wave resistance to oil and gasoline in safety footwear.

Our portfolio for this industry includes the most frequently used additives for footwear: plasticizers (DOP, DOTP), low viscosity BaZn stabilizers (LOX-4M-40), azodicarbonamide with its activator, stearates and soy epoxidized, in partial batches and at a competitive price.

We deliver the commodity in smaller quantities or by full container at a preferential price, keeping it in stock for when your program requires it.

Sub-applications within footwear

Injected sandals

This is the highest-volume and most cost-sensitive product in the entire industry. It's made with a general-purpose plasticizer and a stabilizing system that provides good initial color without increasing the cost of the formula. The discussion here is about pennies per pair, but the color and odor of the finished product are what determine whether the batch is accepted.

Solid and foamed soles

In solid soles, abrasion resistance is paramount, but this is lost when the load becomes too high. In foam soles, the trio of foaming agent, activator, and microspheres defines the density and uniformity of the cells: an uneven cell results in indentations and a sole that deforms with use.

Templates

A flexible and soft component in constant contact with the foot, where odor and fungal growth are the most frequent complaints from end users. Our plasticizers, stabilizers, and antimicrobial additives allow us to formulate a soft insole that also withstands this wear and tear.

PVC boots (slush molding and injection)

Cast boots require a low-viscosity plastisol that flows and gels evenly within the mold; injection-molded boots require a compound that demolds cleanly. Work and safety boots also require resistance to oils, greases, and chemicals, which is achieved through the selection of the plasticizer.

Shoe additives

Resins

FunctionChemical Additives ProductsSpecific application
Medium/low molecular weightK 61 PVC resinInjected sole and sandal
High porosityK 70 PVC ResinInjection molded parts and flexible composites
PasteK76 PVC resin, K76 (H10)Boot by washing and footwear by immersion

Plasticization

FunctionChemical Additives ProductsSpecific application
Primary plasticizerDOP, DOTPGeneral use; restricted phthalate-free DOTP
High molecular weight plasticizer / chemical resistanceTOTMSafety footwear: resists attack from gasoline and oils
Low temperature / flexibilityDOA, DINPCold mixes

Stabilization

FunctionChemical Additives ProductsSpecific application
BaZn low viscosity liquidLOX-4M-40Plastisol for footwear, sandals, boots
CaZn powderMW-188Flexible composites

Foaming and lubrication

FunctionChemical Additives ProductsNote
foaming agentAC-7000Foam sole; it generates the gas that lowers the density. Its fine particle size (3–5 microns) forms a uniform, crack-free cell.
MicrosphereMicrosphereTogether with AZO, it provides a uniform cell structure (prevents cracking and collapse) and reduces yellowing.
Foam activatorZinc Stearate Activates azodicarbonamide
Internal lubricantCalcium StearateDemolding and lubrication
Co-stabilizerEpoxidized Soybean Oil (ESBO)Color stability

Antimicrobial / antifungal protection

FunctionChemical Additives ProductsNote
Antimicrobial agentZinc pyrithioneInsoles, linings and soles: inhibits the growth of bacteria and fungi in parts with constant exposure to moisture, preventing bad odors and material degradation

Optical brightener

FunctionChemical Additives ProductsNote
Optical brightenerOptical brightenerTransparent and light-colored sandals enhance the visual appeal of the finished product

Applicable regulations and certifications

RuleApplicable Chemical AdditivesRelevance
EN 71-3DOTPChildren's footwear and childcare items
Phthalate-freeLOX-4M-40Children's footwear; growing demand from chains and exports
Free of phenol, BPA and nonylphenolMW-188Footwear with toxicological requirements
California Prop 65 — BPA freeLOX-E068-HExport to the United States

Why buy your additives from Chemical Additives

Competitive commodity pricing. DOP, DOTP, epoxidized soybeans and stearates at volume price, which is where the margin of this industry is played out.

Immediate availability in national warehouse. Plasticizers, stabilizers and foaming agents in stock for delivery within 24-72 hours in Mexico.

Partial lots or full container loads at preferential prices. We deliver in the quantity that suits your operation.

One-stop-shop for your footwear formulation. Paste resin, plasticizers, stabilizers, foaming agent, activator and epoxidizing agent from a single supplier.

Backup in crisis. If your usual supplier experiences delays or changes specifications without notice, we'll cover you with qualified material within days.

Common problems with PVC footwear and how to fix them

Low abrasion resistance on the sole.

Overloading is the most frequent cause: it makes the formula cheaper, but you pay for it in durability and returns. RecommendationThe load level can be reduced without losing competitiveness if the rest of the package is readjusted to compensate. We help you find that balance point for your formula.

Cold stiffness.

Recommendation: Incorporate an adipate in a mixture with the general-purpose plasticizer to improve low-temperature flexibility.

Resistance to oils, greases and chemicals (safety footwear).

PVC can be attacked by agents such as gasoline or oil (e.g., palm oil). Recommendation: This resistance can be achieved with catalog products using high molecular weight or polymeric plasticizers; TOTM is a classic example that resists the chemical attack of gasoline and oils. We can help you define the system for your application.

The insole develops a bad smell with use.

Footwear combines moisture, heat, and constant contact with the skin, ideal conditions for bacterial and fungal growth. Recommendation: The problem is addressed at the formulation stage by incorporating a broad-spectrum antimicrobial agent into the product. Contact us to determine the dosage.

If you need commodity stock for your next run, write to us.

Do you need plasticizer or stabilizer for footwear, in stock and at a good price?

Talk to us on WhatsApp.

Do you prefer the finished compound? Chemical Compounds offers sandal compounds and foam profiles. View portfolio.